In this bit by Panasonic though, they say, leaving the doors fully open, exposing the batteries to more oxygen, prolongs life. To my simple mind and limited knowledge of oxidation, it seems like that would shorten the life. Zinc air battery: tips & tricks | Panasonic Batteries >>
This article doesn’t really say exposing the battery to more oxidation prolongs its life. It only says keeping the battery out with open door prolongs life because it prevents drainage if the door is closed.
While I don’t think exposing the battery to more oxidation prolongs its life, I don’t think it shortens is life either. I think the oxidative activates a chemical reaction, and once activated, the Zinc is already oxidated and once oxidated, resealing the hole won’t undo the oxidation process that had already happened.
It’s like getting a sponge wet. If you seal up a wet sponge by putting it inside a sealed bottle, it doesn’t help make the sponge any dryer because the sponge is already holding water inside. In the case of the battery, the Zinc compound is already activated with oxygen and starving it of air while unused, AFTER oxidation already happened, won’t revert or slow down oxidation.
I guess the question here is whether the Zinc compound only needs to be activated initially to work, or whether it continually needs the oxidation to happen to work. My thinking is with the former camp.
I also think that one oxidated, beside the high drainage from the battery, there’s also a slow drainage from a self discharging process. That’s why if left unused after exposed to air, the battery will eventually die even if left unused.